NTP CHEMICAL REPOSITORY (RADIAN CORPORATION, AUGUST 29, 1991)
DIETHYLENE GLYCOL DIACRYLATE
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IDENTIFIERS
CATALOG ID NUMBER: 002182
CAS NUMBER: 4074-88-8
BASE CHEMICAL NAME: DIETHYLENEGLYCOLDIACRYLATE
PRIMARY NAME: DIETHYLENE GLYCOL DIACRYLATE
CHEMICAL FORMULA: C10H14O5
STRUCTURAL FORMULA: (CH2=CHCO2CH2CH2)2O
WLN: 1U1VO2O2OV1U1
SYNONYMS:
ACRYLIC ACID, 2-ETHOXYETHANOL DIESTER
ACRYLIC ACID, OXYDIETHYLENE ESTER
OXYDIETHYLENE ACRYLATE
OXYDIETHYLENE DIACRYLATE
2-PROPENOIC ACID, OXYDI-2,1-ETHANEDIYL ESTER
TGA 2
NK ESTER A 2G
SR 230
PHYSICAL CHEMICAL DATA
PHYSICAL DESCRIPTION: LITERATURE: Clear colorless liquid
REPOSITORY: Clear colorless liquid
MOLECULAR WEIGHT: 214.24
SPECIFIC GRAVITY: 1.11 [058,205]
DENSITY: 1.1110 g/mL @ 25 C [047]
MP (DEG C): Not available
BP (DEG C): >200 C [047,058,205]
SOLUBILITIES:
WATER : 10-50 mg/mL @ 18 C (RAD)
DMSO : >=100 mg/mL @ 18 C (RAD)
95% ETHANOL : >=100 mg/mL @ 18 C (RAD)
METHANOL : Not available
ACETONE : >=100 mg/mL @ 18 C (RAD)
TOLUENE : Not available
OTHER SOLVENTS: Not available
VOLATILITY:
Vapor pressure: 1 mm Hg @ 39 C; 5.5 mm Hg @ 50 C; 26.5 mm Hg @ 75 C [601]
Vapor density : >1 [058]
FLAMMABILITY(FLASH POINT):
This chemical has a flash point of 78 C (172 F) [058,205]. It is
combustible. Fires involving this material can be controlled with a dry
chemical, carbon dioxide or Halon extinguisher.
UEL: Not available LEL: Not available
REACTIVITY:
This chemical is incompatible with strong oxidizers, reducers, peroxides
and other radical initiators [058].
STABILITY:
This chemical polymerizes at high temperatures. It is sensitive to light
[058]. NMR stability screening indicates that solutions of this chemical in
DMSO are stable for at least 24 hours (RAD).
OTHER PHYSICAL DATA:
Boiling point: 94 C @ 0.225 mm Hg [240]
Refractive index: 1.4595 @ 25 C [047,205]
Mild, musty odor [058]
2% Volatile by volume [058]
Evaporation rate: Low [058]
Vapor pressure: 59.0 mm Hg @ 100 C; 210.0 mm Hg @ 150 C [601]
TOXICITY
NIOSH REGISTRY NUMBER: AS9450000
TOXICITY:
typ. dose mode specie amount units other
LD50 orl rat 400 mg/kg
LD50 skn rbt 180 mg/kg
AQTX/TLM96: Not available
SAX TOXICITY EVALUATION:
THR: Poison by skin contact. Moderately toxic by ingestion.
CARCINOGENICITY: Not available
MUTATION DATA:
test lowest dose | test lowest dose
----------- ----------------- | ----------- -----------------
Not available |
TERATOGENICITY: Not available
STANDARDS, REGULATIONS & RECOMMENDATIONS:
OSHA: None
ACGIH: None
NIOSH Criteria Document: None
NFPA Hazard Rating: Health (H): None
Flammability (F): None
Reactivity (R): None
OTHER TOXICITY DATA:
Skin and Eye Irritation Data:
skn-rbt 500 mg SEV
eye-rbt 100 mg SEV
Status: EPA TSCA Chemical Inventory, 1986
EPA TSCA Test Submission (TSCATS) Data Base, September 1989
OTHER DATA (Regulatory)
PROPER SHIPPING NAME (IATA): Poisonous liquids, n.o.s.
(Diethylene glycol diacrylate)
UN/ID NUMBER: UN2810
HAZARD CLASS: 6.1 SUBSIDIARY RISK: None PACKING GROUP: II
LABELS REQUIRED: Poison
PACKAGING: PASSENGER: PKG. INSTR.: 609, Y609 MAXIMUM QUANTITY: 5 L, 1 L
CARGO : PKG. INSTR.: 611 MAXIMUM QUANTITY: 60 L
SPECIAL PROVISIONS: None
USES: Not available
COMMENTS: Not available
HANDLING PROCEDURES
ACUTE/CHRONIC HAZARDS:
This compound is an irritant of the skin and eyes [058]. When heated to
decomposition it emits acrid smoke, acids and noxious gases [043,058].
MINIMUM PROTECTIVE CLOTHING:
If Tyvek-type disposable protective clothing is not worn during
handling of this chemical, wear disposable Tyvek-type sleeves taped to
your gloves.
RECOMMENDED GLOVE MATERIALS:
GlovES+ Expert System Glove Types For The Neat (Undiluted) Chemical:
This chemical has not been tested for permeation by Radian Corporation;
however, the GlovES+ expert system was used to extrapolate permeation test
information from compounds in the same chemical class. The GlovES+ system uses
permeation data from literature sources; therefore, extra safety margins should
be used with the estimated protection time(s). If this chemical makes direct
contact with your glove, or if a tear, puncture or hole develops, replace them
at once.
The GlovES+ expert system is a tool that can help people better manage
protection from chemicals, however this tool cannot replace sound judgment nor
make technical decisions. Our GlovES+ expert system is designed to offer
initial advice and assistance in glove selection while the final glove
selection should be made by knowledgeable individuals based on the specific
circumstances involved.
Glove Type Model Number Thickness Estimated Protection Time
Butyl rubber North B-174 0.68 mm 240 min
PVA Edmont 25-545 0.07 mm 240 min
PE/EVOH/PE Safety4 4H 0.07 mm 240 min
RECOMMENDED RESPIRATOR:
Where the neat test chemical is weighed and diluted, wear a NIOSH-
approved half face respirator equipped with a combination filter cartridge,
i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid
gas, SO2 and a high efficiency particulate filter).
Splash proof safety goggles should be worn while handling this
chemical. Alternatively, a full face respirator, equipped as above,
may be used to provide simultaneous eye and respiratory protection.
OTHER: Not available
STORAGE PRECAUTIONS:
You should protect this material from exposure to light, and store
it under ambient temperatures.
SPILLS AND LEAKAGE:
If you should spill this chemical, use absorbent paper to pick up
all liquid spill material. Seal the absorbent paper, as well as any
of your clothing which may be contaminated, in a vapor-tight plastic
bag for eventual disposal. Wash any surfaces you may have contaminated
with a soap and water solution. Do not reenter the contaminated
area until the Safety Officer (or other responsible person) has verified
that the area has been properly cleaned.
DISPOSAL AND WASTE TREATMENT: Not available
EMERGENCY PROCEDURES
SKIN CONTACT:
IMMEDIATELY flood affected skin with water while removing and isolating
all contaminated clothing. Gently wash all affected skin areas thoroughly
with soap and water.
IMMEDIATELY call a hospital or poison control center even if no symptoms
(such as redness or irritation) develop.
IMMEDIATELY transport the victim to a hospital for treatment after
washing the affected areas.
INHALATION:
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.
IMMEDIATELY call a physician and be prepared to transport the victim to a
hospital even if no symptoms (such as wheezing, coughing, shortness of breath,
or burning in the mouth, throat, or chest) develop.
Provide proper respiratory protection to rescuers entering an unknown
atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA)
should be used; if not available, use a level of protection greater than or
equal to that advised under Respirator Recommendation.
EYE CONTACT:
First check the victim for contact lenses and remove if present. Flush
victim's eyes with water or normal saline solution for 20 to 30 minutes while
simultaneously calling a hospital or poison control center.
Do not put any ointments, oils, or medication in the victim's eyes without
specific instructions from a physician.
IMMEDIATELY transport the victim after flushing eyes to a hospital even if
no symptoms (such as redness or irritation) develop.
INGESTION:
DO NOT INDUCE VOMITING. Corrosive chemicals will destroy the membranes
of the mouth, throat, and esophagus and, in addition, have a high risk of
being aspirated into the victim's lungs during vomiting which increases the
medical problems.
If the victim is conscious and not convulsing, give 1 or 2 glasses of
water to dilute the chemical and IMMEDIATELY call a hospital or poison control
center. IMMEDIATELY transport the victim to a hospital.
If the victim is convulsing or unconscious, do not give anything by mouth,
ensure that the victim's airway is open and lay the victim on his/her side with
the head lower than the body. DO NOT INDUCE VOMITING. Transport the victim
IMMEDIATELY to a hospital.
SYMPTOMS:
Symptoms of exposure to this compound may include irritation of the skin
and eyes, blistering and sensitization [058].
SOURCES
SOURCES:
[015] Lewis, R.J., Sr. and R.L. Tatken, Eds. Registry of Toxic Effects
of Chemical Substances. On-line Ed. National Institute for
Occupational Safety and Health. Cincinnati, OH. AS9450000.
January 9, 1990.
[043] Sax, N.I. and Richard J. Lewis, Sr. Dangerous Properties of Industrial
Materials. 7th Ed. Van Nostrand Reinhold. New York. 1989.
Vol. II, p. 72, #ADT250.
[047] Weast, R.C. and M.J. Astle, Eds. CRC Handbook of Data on
Organic Compounds. CRC Press, Inc. Boca Raton, FL.
1985. Vol. I, p. 556, #D00375.
[058] Information Handling Services. Material Safety Data Sheets
Service. Microfiche Ed. Bimonthly Updates. August/September
1989. #7021-017, C-01; #7975-003, B-02.
[082] U.S. Environmental Protection Agency, Office of Toxic Substances.
Toxic Substances Control Act Chemical Substance Inventory: 1985
Edition. 5 Vols. U.S. Environmental Protection Agency.
Washington, D.C. January 1986. Listed.
[110] Oak Ridge National Laboratory. Environmental Mutagen Information
Center (EMIC), Bibliographic Data Base. Oak Ridge National
Laboratory. Oak Ridge, TN. Not listed.
[120] Oak Ridge National Laboratory. Environmental Teratogen Information
Center (ETIC), Bibliographic Data Base. Oak Ridge National
Laboratory. Oak Ridge, TN. Not listed.
[205] Dean, John A., Ed. Lange's Handbook of Chemistry. 13th Ed.
McGraw-Hill Book Company. New York. 1985. p. 7-306, #d574.
[240] Grayson, Martin, Ed. Kirk-Othmer Encyclopedia of Chemical Technology.
Volumes 1-24 and Supplement. 3rd Ed. John Wiley & Sons. New York.
1978-1984. Vol. 1, p. 333; Vol. 17, p. 697.
[430] Clayton, G.D. and F.E. Clayton, Eds. Patty's Industrial Hygiene
and Toxicology. Vol. 2. Third Revised Edition. John Wiley
and Sons. New York. 1981. Vol. IIC, p. 4013.
[601] Safety Consulting Engineers Inc. Vapor Pressure Test Results for
Twelve Materials. Report Number 21150-LR. Safety Consulting
Engineers Inc. Rosemont, IL. August 31, 1989.
[610] Clansky, Kenneth B., Ed. Suspect Chemicals Sourcebook: A Guide to
Industrial Chemicals Covered Under Major Federal Regulatory and
Advisory Programs. Roytech Publications, Inc. Burlingame, CA.
1990. Not listed.
[620] United States National Toxicology Program. Chemical Status Report.
NTP Chemtrack System. Research Triangle Park, NC. November 6, 1990.
Not listed.
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